FRET-Mediated Collective Blinking of Self-Assembled Stacks of CdSe Semiconducting Nanoplatelets

نویسندگان

چکیده

Förster resonant energy transfer (FRET) can be an efficient mechanism between densely packed fluorescent emitters. It plays a key role in photosynthesis but may also detrimental. In optoelectronic devices for instance, FRET funnels to quenching sites and favors losses. Here, we image individual self-assembled chains of stacked CdSe nanoplatelets demonstrate fluorescence intermittency (blinking) chain portions corresponding few tens platelets. This collective blinking is attributed the fluctuations quencher site, which excitons are transferred by migration from surrounding We develop analytical random walk model show that ensemble platelets quenched collectively single site provided its (nonradiative recombination) rate faster than geometric mean radiative recombination rate, would order (100 ps)−1.

برای دانلود باید عضویت طلایی داشته باشید

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

Shape control of zincblende CdSe nanoplatelets.

The lateral dimensions of CdSe nanoplatelets have a strong and unique influence on their opto-electronic properties, with sizes that can be tuned from the weak to the strong exciton confinement regime. There are state-of-the-art reports on several nanoplatelet syntheses; however, at present only the thickness is well-controlled. We demonstrate here that we can achieve a control over the aspect ...

متن کامل

ShRNA-mediated knock-down of CD200 using the self-assembled nanoparticle-forming derivative of polyethylenimine

Objective(s): ShRNA-mediated silencing strategy is considered to be a potent therapeutic approach. The present study aimed to assess the ability of the previously prepared polyethylenimine (PEI) derivative for the shRNA knock-down of the CD200 gene on the cells obtained from the patients with chronic lymphocytic leukemia (CLL). Materials and Methods: Since there are several investigations...

متن کامل

Surface passivation of semiconducting oxides by self-assembled nanoparticles

Physiochemical interactions which occur at the surfaces of oxide materials can significantly impair their performance in many device applications. As a result, surface passivation of oxide materials has been attempted via several deposition methods and with a number of different inert materials. Here, we demonstrate a novel approach to passivate the surface of a versatile semiconducting oxide, ...

متن کامل

Self-assembled lamellar MoS2, SnS2 and SiO2 semiconducting polymer nanocomposites.

Lamellar nanocomposites based on semiconducting polymers incorporated into layered inorganic matrices are prepared by the co-assembly of organic and inorganic precursors. Semiconducting polymer-incorporated silica is prepared by introducing the semiconducting polymers into a tetrahydrofuran (THF)/water homogeneous sol solution containing silica precursor species and a surface-active agent. Semi...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

ژورنال

عنوان ژورنال: ACS Photonics

سال: 2023

ISSN: ['2330-4022']

DOI: https://doi.org/10.1021/acsphotonics.2c01441